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Abstract: The dynamic properties of glassy polymers are well-known to change up confinement to the nanoscale. Confinement to free-standing thin films leads to an enhancement in the segmental dynamics, and changes in the chain conformation lead to changes in the entanglement density in confined polymers. In this study, we investigate the role of both segmental […] |
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Abstract: The field of heterogeneous catalysis has been prompted to shift toward designing catalysts that can perform beneficial chemistries at ambient conditions. Such materials should have high activity and stability and avoid issues prevalent in other traditional catalysts that are not earth-abundant, chemically efficient, or with high selectivity to carry out these reactions. In this […] |
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