Abstract: Highly loaded, polymer-infiltrated nanoparticle films (PINFs) enable the synergistic combination of polymers with the functionality of nanoscale fillers. Extensive studies have found that their behavior deviates markedly from bulk polymers due to extreme confinement and high interfacial area within the interstitial pore network. However, incorporating polymer blends in these PINFs (blend-PINFs) is unexplored. Confinement […]
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Abstract: Metamaterials are engineered materials designed to manipulate and tailor electromagnetic (EM) waves. Metasurfaces are planar metamaterials that rely on inclusions whose optical properties and spatial arrangements are designed to interact with incident EM waves to yield desired reflected or transmitted waveforms. A reconfigurable metasurface in which the relative positions of inclusions can be controlled […] |
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Abstract: Solvated macromolecules such as proteins and polymers undergo conformational changes in response to stimuli such as pressure, temperature, pH, ligand binding, and post-translational modification. These transitions are fundamental to biological function, from cellular signaling to misfolding and aggregation, and are increasingly harnessed in applications such as drug delivery, biosensing, and biomaterials design. Understanding how […]
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Abstract: Micron-scale colloidal particles with short-ranged attractions, e.g., colloids functionalized with single-stranded DNA oligomers, have emerged as a powerful platform for studying colloidal self-assembly phenomena with the long-term goal of identifying routes for metamaterial fabrication. Although these systems have been investigated extensively both experimentally and computationally, the role of ‘real world’ features that may impact […] |
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